As I was inspired to think about this after reading another comment on it.
Personally "Murky" is 24 volt base vehicle with 12 volt habitation wiring.
The New build "Betty" again is a 24 volt base vehicle, but nothing has been done that would steer me one way or another.
What are your opinions and why?
Mark
There are pros and cons to both options.
The way I see it, if you have a 24V vehicle, having a 24V Leisure Battery setup will let you:
Easier Bi-Directional Charging from Vehicle to Leisure and Vice Versa - you just need one voltage standard for charging and don't have to convert up or down. You can if you prefer use a basic relay or mechanical switch to connect the two systems rather than voltage converters.
This allows you to have a simple split-charge system for Alternator charging of Lesiure Batteries, or EHU and Solar charging can feed the Starter Battery as well as the Leisure Battery in as simple a way as on a 12V Vehicle/12V Habitation setup.
You can get a bigger solar harvesting on a given Solar Controller at 24V compared to 12V as almost all are current limited more than they are power limited. This means either more panels on the same controller, or you can use a 'smaller' (cheaper) controller. On larger PV arrays, the Controller saving when going into a 24V system compared to a 12V system can actually be pretty significant.
Higher Voltage and Lower Current (to achieve the same power) means you can use thinner cable if you want; and for a given cable gauge, you get less losses at the higher voltage.
If you want to use an inverter, you pull less current from the battery - that means you really can get away with a lesser gauge DC cable (which can be pretty significant when it comes to inverter levels of power).
Downsides - you will need some 12V circuits almost certainly, so will need a DC-DC converter in the picture.
You need a 24V battery array of course - so you will need an even number of batteries (so multiples of 2 12V ones, or multiples of 4 6V ones) - This could be awkward in some cases (for example, I changed my 4 x 12V batteries earlier this year to a bank of 3 x 12V batteries. If I has been setup at 24V, I could not have used 3 batteries).
Having said that, when you have a pair of 12V batteries, either setup in Parallel (for a 12V system) or Series (24V system), it is much easier to keep an eye on the batteries when in 24V/Series and make sure they stay balanced compared to doing that on a 12V/Parallel setup.